In-mold coating

ABSTRACT

An FRP molding can be in-mold coated using a free radical peroxide initiated thermosetting composition of at least one polymerizable epoxy based oligomer having at least two acrylate groups, at least one copolymerizable ethylenically unsaturated monomer, at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH 2 , --NH-- and/or --OH group, polyvinyl acetate, at least one zinc salt of a fatty acid having at least 10 carbon atoms, at least one accelerator for a peroxide initiator, conductive carbon black, a filler such as talc and a copolymerizable or cocurable compound selected from the group consisting of 
     (I) at least one polyoxyalkylene glycol oligomer having two acrylate groups and 
     (II) at least one polyurethane oligomer having two acrylate groups and mixtures of (I) and (II). 
     Optionally and desirably, there additionally can be added to the foregoing composition at least one calcium salt of a fatty acid.

This is a division of application Ser. No. 435,026 filed Oct. 25, 1982 now U.S. Pat. No. 4,414,173, which is a continuation-in-part of prior copending U.S. patent application Ser. No. 316,592 filed Nov. 2, 1981, now abandoned.

This invention relates to a thermosetting in-mold coating composition useful for in-mold coating a molded fiberglass reinforced thermoset plastic such as a polyester resin or a vinyl ester resin (FRP) molding or part that usually does not require the combining of two or more components immediately prior to use.

BACKGROUND OF THE INVENTION

A major deficiency of compression molded thermoset glass fiber reinforced polyester (FRP) moldings is surface imperfections such as pits, pores, surface cracks, waviness and sink marks. The in-mold coating process of U.S. Pat. No. 4,081,578 generally overcomes these imperfections by molding a low viscosity thermoset on top of the FRP in a second molding operation. The composition described in U.S. Pat. No. 4,081,578 contains free hydroxyl as well as isocyanate groups that co-react at room temperature, resulting in a limited (about one-half hour) pot life. In practice, the reactive ingredients are kept apart, and combined only immediately prior to application. This necessitates dual pumping equipment and an accurate metering device, which increase the cost and complexity of the system. A single component coating would thus offer a significant advantage. Moreover, conductive carbon black does not dispense well in isocyanate based in-mold coating compositions, and it is difficult to obtain after in-mold coating and subsequent electrostatic painting, a paint layer which is even.

Therefore, it is an object of this invention to avoid the difficulties alluded to and to provide a process for in-mold coating an FRP molding with a one-component coating composition.

Another object of this invention is to provide a composition suitable for in-mold coating an FRP molding.

A further object of this invention is to provide a cured molded FRP molding or part with an adherent coating in-mold coated with a one component in-mold coating composition.

These and other objects and advantages of the present invention will become more apparent to those skilled in the art from the following detailed description and working examples.

SUMMARY OF THE INVENTION

According to the present invention a FRP molding can be in-mold coated using a one-component free radical initiated thermosetting composition of

(a) 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500,

(b) from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer,

(c) from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH₂, --NH-- and/or --OH group,

(d) from about 20 to 90 parts by weight of polyvinyl acetate,

(e) from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms,

(f) from about 0.01 to 1.0 part by weight of at least one accelerator for a peroxide initiator,

(g) from about 5 to 30 parts by weight of conductive carbon black,

(h) from about 50 to 155 parts by weight of a filler and

(i) from about 5 to 120 parts by weight of a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being selected from the group consisting of

(I) at least one polyoxyalkylene glycol based oligomer having two acrylate groups and

(II) at least one polyurethane based oligomer having two acrylate groups and mixtures of (I) and (II).

Optionally and desirably, there additionally can be added to the foregoing composition (j) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight.

An organic free radical peroxide initiator is used in the composition in an amount of up to about 5%, preferably up to 2%, by weight based on the weight of the polymerizable ethylenically unsaturated materials.

The composition flows well and is stable for about a week even when containing the peroxide. It can be molded in a short period of time. The resulting thermoset coating exhibits good adhesion to different FRP substrates and will accept many paint finishes obviating the need for a primer.

Also, the carbon black disperses well throughout the composition to provide on curing an in-mold coating which can be spray painted electrostatically to provide an even paint coating or film. The present coating, moreover, thus generally eliminates any subsequent step of priming the in-mold coating with a conductive primer before electrostatic painting.

DISCUSSION OF DETAILS AND PREFERRED EMBODIMENTS

The polymerizable epoxy based oligomer having at least two acrylate (or methacrylate or ethacrylate) groups is prepared by reacting acrylic acid, methacrylic acid or ethacrylic acid and so forth with an epoxy based oligomer or resin such as a Bisphenol A epoxy, a tetrabromo Bisphenol A epoxy, phenolic novolak epoxy, tetraphenylolethane epoxy, dicycloaliphatic epoxy and so forth. Mixtures of these epoxy based oligomers may be used. Of these materials it is preferred to use a diacrylate terminated Bisphenol A epoxy oligomer. They have weight average molecular weights of from about 500 to 1,500. These materials are well known. For more information on these materials see "Heat Resistant Vinyl Ester Resin," M. B. Launikitis, Technical Bulletin, SC:116-76, Shell Chemical Company, June, 1976 and Shell Chemical Company Technical Bulletins SC:16-76 and SC:60-78.

A copolymerizable ethylenically unsaturated monomer is used to copolymerize with and to crosslink the polymerizable oligomers and includes styrene (preferred), alpha methyl styrene, vinyl toluene, t-butyl styrene, chlorostyrene, methyl methacrylate, diallyl phthalate (with styrene or methyl methacrylate and the like), trially cyanurate, triallyl isocyanurate, divinyl benzene, methyl acrylate and so forth and mixtures thereof. The unsaturated monomer is used in an amount of from about 80 to 160 parts by weight per 100 parts by weight of the polymerizable epoxy based oligomer.

For further copolymerization and crosslinking and to improve hardness of the resulting coating there is used in the in-mold coating composition a monoethylenically unsaturated compound having a ##STR1## group and having a --NH₂, --NH-- and/or --OH group. Examples of such monomeric compounds are hydroxyl propyl methacrylate (preferred), hydroxyethyl methacrylate, hydroxy ethyl acrylate, hydroxy ethyl crotonate, hydroxypropyl acrylate, hydroxy polyoxypropylene acrylate, hydroxy polyoxypropylene methacrylate, hydroxy polyoxyethylene methacrylate, acrylamide, methacrylamide, N-hydroxymethyl acrylamide, N-hydroxymethyl methacrylamide and so forth and mixtures of the same. These compounds are used in an amount of from about 10 to 120 parts by weight per 100 parts by weight of the polymerizable epoxy based oligomer.

Polyvinyl acetate is employed in the in-mold composition to improve paint adhesion of the in-mold coating to the substrate. The polyvinyl acetate is employed in a minor amount by weight as compared to the total weight of the ethylenically unsaturated materials in the in-mold coating composition and sufficient for paint adhesion. The polyvinyl acetate is employed in an amount of from about 20 to 90 parts by weight per 100 parts by weight of the epoxy based polymerizable oligomer.

A zinc salt of a fatty acid having at least 10 carbon atoms, also, is employed in the in-mold coating composition and appears to function as a mold release agent and as a secondary accelerator for the cure. Fatty acids are well known. See "Organic Chemistry," Fieser and Fieser, D. C. Heath and Company, Boston, 1944, pages 88, 381-390, 398 and 401 and "Hackh's Chemical Dictionary," Grant, McGraw Hill Book Company, New York, 1969, page 261. Mixtures of zinc salts of the fatty acids can be used. Examples of some zinc salts are zinc palmitate, zinc stearate, zinc ricinoleate and the like. It is preferred to use the zinc salt of a saturated fatty acid such as zinc stearate. See, also, "Whittington's Dictionary Of Plastics," Whittington, Technomic Publishing Co., Inc., Stamford, Conn., 1968, pages 35, 102 and 261. The zinc salt is used in an amount from about 0.2 to 5 parts by weight per 100 parts by weight of the polymerizable epoxy based oligomer.

An accelerator is used for the peroxide initiator and is a material such as a drier, e.g., cobalt octoate (preferred). Other materials which may be used are zinc naphthenate, lead naphthenate, cobalt naphthenate and manganese naphthenate. Soluble Co, Mn and Pb salts of linoleic acid, also, may be used. Mixtures of accelerators may be used. The accelerator is used in an amount of from about 0.01 to 1 part by weight per 100 parts by weight of the polymerizable epoxy based oligomer.

Conductive carbon black is used in the in-mold coating composition in an amount of from about 5 to 30 parts by weight per 100 parts by weight of the polymerizable epoxy based oligomer.

A filler is used in the in-mold coating composition in an amount of from about 50 to 155 parts by weight per 100 parts by weight of the polymerizable epoxy based oligomer. Examples of fillers are clay, MgO, Mg(OH)₂, CaCO₃, silica, calcium silicate, mica, aluminum hydroxide, barium sulfate, talc, hydrated silica, magnesium carbonate and mixtures of the same. The fillers should be finely divided. Of these fillers it is preferred to use talc. Fillers can afford the desired viscosity and flow to the in-mold composition for molding and contribute to the desired physical properties in the resulting thermoset in-mold coating. Fillers, also, may improve adhesion. However, care should be exercised in the use of high filler contents as this may give high viscosities and result in flow and handling difficulties.

There further is employed in the in-mold coating composition a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000, in an amount of from about 5 to 120 parts by weight per 100 parts by weight of the polymerizable epoxy based oligomer, and being selected from the group consisting of

(I) at least one polyoxyalkylene glycol based oligomer having two acrylate groups and

(II) at least one polyurethane based oligomer having two acrylate groups and mixtures of (I) and (II).

Examples of said diacrylate compounds (I) include triethylene glycol diacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol diacrylate, polypropylene glycol diacrylate, polyethylene glycol dimethacrylate or polyoxyethylene glycol dimethacrylate (preferred), polypropylene glycol dimethacrylate, polyethylene propylene glycol diacrylate, and so forth and mixtures thereof. These acrylates are made by reacting polyoxyalkylene glycols such as polypropylene ether glycol with acrylic acid, methacrylic acid and the like. Since some of these reactive difunctional materials may be made by reacting unsaturated acids and alcohols, they may contain some OH and/or COOH groups.

Examples of said diacrylate compounds (II) for use in said in-mold coating composition include a polyesterurethane diacrylate, a polyetherurethane diacrylate or a polyesteretherurethane diacrylate or other polyurethane oligomer having two acrylate groups. These materials may be made by reacting a polyetherdiol (e.g., a polypropylene ether diol), polyesterdiol (e.g., a polyethylene adipate diol) and/or a polyetherester diol (e.g., a polypropylene ether adipate diol), and so forth with a diisocyanate like tolyene diisocyanate, 4,4'-diphenylmethane diisocyanate, hexamethylene diisocyanate and the like in an amount sufficient to form a diisocyanate terminated polyurethane prepolymer which is then reacted with hydroxy propyl acrylate, hydroxy ethyl acrylate, hydroxy ethyl methacrylate and so forth to form the diacrylate terminated polyurethane oligomer or polymer. Mixtures of these acrylate terminated polyurethane oligomers may be used. The term "acrylate" as used here is intended to cover methacrylate and ethacrylates as well as acrylates. Of these materials it is preferred to use a diacrylate polyesterurethane oligomer. Acrylate terminated polyurethane oligomers, e.g., curable by light, ultraviolet, electric beam and/or infrared and so forth, are well known, and sometimes are referred to as irradiation or radiation curable materials.

The diacrylate compounds (I) and/or (II), above, appear to improve the hardness of and reduce the brittleness of the in-mold coating.

Optionally and desirably also a calcium salt of a fatty acid having at least 10 carbon atoms, from about 0.2 to 5 parts by weight of calcium salt per 100 parts by weight of the polymerizable epoxy based oligomer, can be used in the in-mold coating composition as a mold release agent and to control the rate of the cure. Fatty acids are well known, see above. Mixtures of calcium salts of the fatty acids can be used. Examples of some calcium salts are calcium stearate, calcium palmitate, calcium oleate and the like. It is preferred to use the calcium salt of a saturated fatty acid like calcium stearate.

An organic free-radical or free radical generating initiator (catalyst) such as a peroxide is used to catalyze the polymerization, copolymerization and/or crosslinking of the ethylenically unsaturated oligomers and the other ethylenically unsaturated materials. Examples of free-radical initiators include tertiary butyl perbenzoate, tertiary butyl peroctoate in diallyl phthalate, diacetyl peroxide in dimethyl phthalate, dibenzoyl peroxide, di(p-chlorobenzoyl) peroxide in dibutyl phthalate, di(2,4-dichlorobenzoyl) peroxide with dibutyl phthalate, dilauroyl peroxide, methyl ethyl ketone peroxide, cyclohexanone peroxide in dibutyl phthalate, 3,5-dihydroxy-3,4-dimethyl-1,2-dioxacyclopentane, t-butylperoxy(2-ethyl hexanoate), caprylyl peroxide, 2,5-dimethyl-2,5-di(benzoyl peroxy) hexane, 1-hydroxy cyclohexyl hydroperoxide-1, t-butyl peroxy (2-ethyl butyrate), 2,5-dimethyl-2,5-bis(t-butyl peroxy) hexane, cumyl hydroperoxide, diacetyl peroxide, t-butyl hydroperoxide, ditertiary butyl peroxide, 3,5-dihydroxy-3,5-dimethyl-1,2-oxacyclopentane, and 1,1-bis(t-butyl peroxy)-3,3,5-trimethyl cyclohexane and the like and mixtures thereof. It is desirable sometimes to use mixtures of initiators to take advantage of their different decomposition rates and times at different temperatures and so forth. A preferred initiator to use is tertiary butyl perbenzoate. The peroxide initiator should be used in an amount sufficient to overcome the effect of the inhibitor and to cause crosslinking or curing of the ethylenically unsaturated materials. In general the peroxide initiator is used in an amount of up to about 5%, preferably up to about 2%, by weight based on the weight of the ethylenically unsaturated materials employed in the in-mold coating composition.

The unsaturated materials mentioned above, thus, are used in an amount sufficient to provide on cure (e.g., polymerization, copolymerization and/or crosslinking) a thermoset composition.

To prevent premature gelation of the ethylenically unsaturated materials and to provide for improved shelf-life or storageability inhibitors are added in the desired amount to the composition or are provided in the raw materials before use. Examples of inhibitors are hydroquinone, benzoquinone, p-t-butyl catechol and the like and mixture thereof.

The in-mold composition additionally optionally may be compounded with other mold release agents, antidegradants, U-V absorbers, paraffin wax, solid glass or resin micro-spheres, thickening agents, low shrink additives and the like. These compounding ingredients should be used in amounts sufficient to provide satisfactory results. It is not desirable to use in the in-mold composition of this invention materials like butadiene-styrene block copolymers or fatty alcohol phosphates.

For ease in handling, materials like polyvinylacetate may be dissolved in a reactive monomer like styrene. The viscosity of the oligomers may be reduced by dilution with styrene and the like. The ingredients of the in-mold composition should be readily mixed and handled at ambient or room temperature or temperatures below the polymerization temperature so that they may be readily pumped to the mold and injected into the same. The ingredients may be warmed or heated before or during mixing and mixed in steps to facilitate thorough mixing, dispersion and solution of the same. Also, the bulk of the ingredients can be thoroughly mixed and the remainder including the catalyst separately mixed and then both can be pumped to a mixing bead to be mixed together and then injected into the mold.

With the peroxide initiator or catalyst the in-mold composition exhibits a shelf-life at room temperature (about 25° C.) of about a week, and without the initiator it exhibits a shelf life of several months at room temperature. The initiator is preferably added to the composition and thoroughly mixed therewith just before molding.

All of the ingredients of the in-mold coating composition should be kept dry or have a minimal amount of moisture or the water content should be controlled to obtain reproducible results and to prevent pore formation.

Mixing of the ingredients of the in-mold composition should be thorough. Injection or compression, transfer molding, or other molding apparatus or machines can be used for the in-mold coating. Molding apparatus and methods may be found in U.S. Pat. Nos. 4,076,780; 4,076,788; 4,081,578; 4,082,486; 4,189,517; 4,222,929; 2,245,006; 4,239,796; 4,239,808 and 4,331,735. Please see, also, "Proceedings of the Thirty-Second Annual Conference Reinforced Plastics/Composites Institute," SPI, Washington, February 1977, Griffith et al, Section 2-C, pages 1-3 and "33rd Annual Technical Conference, 1978 Reinforced Plastics/Composites Institute The Society of the Plastics Industry, Inc.," SPI, Ongena, Section 14-B, pages 1-7. The in-mold coating composition can be applied to the substrate and cured at a temperature of from about 290° to 310° F., and at a pressure of about 1000 p.s.i. for from about 0.5 to 3 minutes.

The processes and products of the present invention can be used in the manufacture of automobile parts such as grille and headlamp assemblies, deck hoods, fenders, door panels and roofs as well as in the manufacture of food trays, appliance and electrical components, furniture, machine covers and guards, bathroom components, structural panels and so forth. The glass fiber reinforced thermoset plastic (FRP) such as the polyester resin or vinyl ester resin and glass fiber composition substrate to which the in-mold composition is applied can be a sheet molding compound (SMC) or a bulk molding compound (BMC), or other thermosetting FRP material as well as a high strength molding compound (HMC) or a thick molding compound. The FRP substrate can have from about 10 to 75% by weight of glass fibers. The SMC compound usually contains from about 25 to 30% by weight of glass fibers while the HMC compound may contain from about 55 to 60% by weight of glass fibers. The glass fiber reinforced thermoset plastic (FRP) substrate can be rigid or semirigid (may contain a flexibilizing moiety such as an adipate group in the polyester). The substrate, also, may contain other flexibilizing polymers, the elastomers and plastomers, such as the styrene-butadiene block copolymers. Unsaturated polyester glass fiber thermosets are known as shown by "Modern Plastics Encyclopedia," 1975-1976, October, 1975, Vol. 52, No. 10A, McGraw-Hill, Inc., New York, pages 61, 62 and 105 to 107; "Modern Plastics Encyclopedia," 1979-1980, October, 1979, Volume 56, Number 10A, pages 55, 56, 58, 147 and 148 and "Modern Plastics Encyclopedia," 1980-81, October, 1980, Volume 57, Number 10A, pages 59, 60, and 151 to 153, McGraw-Hill, Inc., New York, N.Y. for information on vinyl ester resins see the Shell Chemical Company Technical Bulletins mentioned above.

The compositions of the present invention can exhibit good pumpability and flow in the mold. They can give rapid cures as low as 75 to 90 seconds at 300° F. They, also, show good adhesion to paints and can be used not only as an in-mold coating to cover blemishes but as a good conductive coating for electrostatic painting and as a primer for most paint finish systems such as soluble acrylic lacquers, acrylic dispersion lacquers, water borne acrylic enamels, high solids solution acrylic enamels, acrylic non-aqueous dispersions and urethanes.

The following examples will serve to illustrate the present invention with more particularity to those skilled in the art. In these examples, the parts are parts by weight unless otherwise indicated.

EXAMPLE 1

The following ingredients were mixed together to form in-mold coating compositions:

    ______________________________________                                                  Parts by Weight                                                       Ingredient A         B      C      D    E                                      ______________________________________                                         LP 90      150       150    150    150  225                                    UVITHANE 783                                                                              150       180    180    225  150                                    CHEMLINK 600                                                                              180        90    --     --    90                                    Hydroxypropyl                                                                             --         90    --     90   180                                    methacrylate                                                                   Styrene     90       135     51    90    45                                    2% Benzoquinone                                                                           13.5       15     9     12    15                                    in styrene                                                                     ______________________________________                                    

Then the following ingredients were mixed in:

    ______________________________________                                         Zinc stearate                                                                              1.62     1.8   1.08   1.53 1.89                                    Cobalt octoate                                                                             .54      .6    .36    .51  .63                                     (12% as Co in                                                                  mineral oil)                                                                   ______________________________________                                    

The following ingredients were then mixed in:

    ______________________________________                                         VULCAN Carbon Black                                                                             27     30     18  25.5  31.5                                  Talc (630)      159    180    108  156   192                                   ______________________________________                                    

Properties of uncatalyzed compositions:

    ______________________________________                                         Brookfield viscosity (cps)                                                                     8800   6200   16000 8400 7600                                  at 86° F., #7 spindle                                                   at 100 rpm                                                                     ______________________________________                                    

To each composition 1 part by weight of the initiator TBPB was added per 100 parts by weight of the total in-mold composition.

The in-mold compositions exhibited the following properties:

    ______________________________________                                         Gel Time at 230° F.                                                                 7.3/330 9.1/336 4.5/316                                                                              7.7/318                                                                              14.4/320                               minutes/peak                                                                   temp. °F.                                                               ______________________________________                                    

The above compositions were then in-mold coated onto substrates of molded thermoset conventional polyester-styrene-glass fibers compositions (about 25% glass fibers) containing in some instances additionally a butadiene-styrene block copolymer at 1,000 psi and 300° F. for about 2 minutes. The overall results obtained for the cured in-mold coating compositions are shown below:

    ______________________________________                                         Hot strength                                                                              Poor     Poor    Fair   Fair  Poor                                  (Maintenance of coating integrity on opening                                   mold, e.g., resistance to scratching and scuffing                              an to delamination on opening the mold.)                                       Adhesion to                                                                               Pass     Pass    Marginal                                                                              Marginal                                                                             Pass                                  substrate                   at best                                                                               to pass                                     Phase separation                                                                          Yes      Yes     Yes    None  Yes                                   (Surface   (minor)  (minor?)                                                   continuity or                                                                  appearance of                                                                  coating                                                                        Conductivity                                                                              160-165  165+    150-160                                                                               155   165+                                  (Ransberg                                                                      meter reading)                                                                 Hardness, pencil                                                                          Fails    Pass    Pass   Pass  Pass                                  ASTM D3363-74                                                                             B        HB      2H     2H    HB                                    Finish Properties                                                                         Good     Good    Poor*  Good  Good                                  (Paint                                                                         Acceptability)                                                                 ______________________________________                                          *To water based acrylics. Good for acrylic lacquers.                     

EXAMPLE 2

The method of this example was similar to that of Example 1, above, except for the noted changes. The results obtained on in-mold coating were satisfactory.

The following ingredients were mixed together to form in-mold coating compositions:

    ______________________________________                                                               Parts By Weight                                          ______________________________________                                         Ingredient              F       G                                              ______________________________________                                         LP 90                   75      100                                            UVITHANE 783            100     75                                             CHEMLINK 600            --      25                                             Hydroxypropyl           30      20                                             Methacrylate                                                                   Styrene                 30      10                                             2% Benzoquinone          5       5                                             in styrene                                                                     Then the following ingredients were mixed in:                                  Zinc stearate           .675    .675                                           Cobalt octoate          .225    .225                                           (12% as Co in                                                                  mineral oil)                                                                   Calcium stearate        .675    .675                                           The following ingredients were then mixed in:                                  VULCAN carbon black     11      11                                             Talc                    70      70                                             ______________________________________                                    

To each composition 1 part by weight of the initiator TBPB was added per 100 parts by weight of the total in-mold composition.

The resulting in-mold compositions, F and G, passed all of the tests shown for Runs A to E of Example 1, above. However, in-mold composition F had fair hot strength properties while in-mold composition G had poor hot strength properties.

EXAMPLE 3

This example illustrates a method for preparation of the in-mold coating composition prior to in-mold coating and curing. The ingredients were mixed in the order as shown below:

    ______________________________________                                         LP 90               100.0 pbw                                                  CHEMLINK 600        25.0 pbw                                                   Hydroxypropyl Methacrylate                                                                         20.0 pbw                                                   2% Benzoquinone in Styrene                                                                          5.0 pbw                                                   ______________________________________                                    

1. Charge these materials to the reactor and blend.

    ______________________________________                                         Styrene           5.0 pbw         6.55 pbw                                     Zinc Stearate     0.675 pbw                                                    Calcium Stearate  0.675 pbw                                                    Cobalt Octoate (12% as                                                                           0.200 pbw                                                    Co in mineral oil)                                                             ______________________________________                                    

2. Pre-blend the above materials and charge to the reactor. After adding the above charge, heat to 44° C. (110° F.) while mixing.

    ______________________________________                                         UVITHANE 783 (Preheated to 49° C.)                                                             75.0 pbw                                                ______________________________________                                    

3. Add the UVITHANE 783 to the reactor and mix until the material is uniform. Cool to 38° C. (100° F.).

    ______________________________________                                         VULCAN carbon black                                                                               11.0 pbw                                                    ______________________________________                                    

4. Add the carbon black to the reactor and mix for 30 minutes. Hold the temperature at 38° C. (100° F.).

    ______________________________________                                         Talc (BEAVER WHITE 200)                                                                             70.0 pbw                                                  ______________________________________                                    

5. Add the talc to the reactor and mix for 1 hour while holding the temperature at 38° C. (100° F.). Remove sample.

Brookfield Viscosity (cps) 86° F., #7 Spindle @ 100 rpm, 13,000-15,000.

6. Check the gel time. If below 8 minutes, add 1 pbw of 2% benzoquinone in styrene and mix for 30 minutes. Recheck the gel time. Repeat the above procedure until the gel time is between 8 to 10 minutes.

    ______________________________________                                         Gel Time, *230° F.                                                                       8-10 minutes                                                  ______________________________________                                          *1.0 pbw of TBPB/100 pbw total composition. When making up material for        checking the gel time, weigh out 100.0 gms total composition and add 1.00      gm of TBPB and mix thoroughly before running gel test.                   

7. Subtract the total number of the pbw of 2% benzoquinone in styrene additions made from the number 5 and add the difference as styrene. Mix for 30 minutes, degas for 15 minutes and filter through a 60 mesh screen. Store at 45° F. pbw--parts by weight.

EXAMPLE 4

The method of this example was similar to the preceding examples, and the following in-mold coating compositions were prepared:

    ______________________________________                                                   Parts by Weight                                                                H      I        J        K                                           ______________________________________                                         Ingredient                                                                     LP-90       100      100      100    100                                       EPOCRYL 370 75                                                                 CHEMPOL 4825         75                                                        UVIMER 580                    75                                               ALTAC 382 E                          75                                        CHEMLINK 600                                                                               25       25       25     25                                        Hydroxypropyl                                                                              20       20       20     20                                        methacrylate                                                                   Styrene     10       10       10     10                                        2% benzoquinone                                                                             5        5        5      5                                        in styrene                                                                     Zinc stearate                                                                              0.675    0.675    0.675  0.675                                     Calcium stearate                                                                           0.675    0.675    0.675  0.675                                     Cobalt octoate                                                                             0.225    0.225    0.225  0.225                                     (12% as Co in                                                                  mineral oil)                                                                   VULCAN      11       11       11     11                                        carbon black                                                                   BEAVER WHITE                                                                               70       70       70     70                                        200, Talc                                                                      Brookfeild viscosity                                                                       12,800   10,200   --     --                                        (cps) at 86° F., #7                                                     spindle at 100 rpm                                                             ______________________________________                                         To each composition 1 part by weight of the initiator TBPB                     was added per 100 parts by weight of the total in-mold coating                 composition.                                                                   ______________________________________                                         Gel Time at 230° F.                                                                 5.75/314 8.3/324  15.9/322                                                                              8.7/323                                   In-mold coating properties on molded thermoset glass fiber-                    polyester-styrene substrates:                                                  ______________________________________                                         Hot Strength                                                                               Excellent                                                                               Fair     Good   --                                        Adhesion (scalpel, a                                                                       Pass     Pass     Fail   --                                        severe test) to                                                                substrate                                                                      Release from mold                                                                          Good     Good     Good   Did not mold                                                                   mold                                                                           well - poor                                                                    flow along                                                                     with poor                                                                      release                                   Phase separation                                                                           None     None     None   --                                        Conductivity                                                                               165      160-165  165    --                                        (Ransberg meter                                                                reading)                                                                       ______________________________________                                    

EXAMPLE 5

The method of this example was similar to the preceding examples, and the following in-mold coating compositions were prepared:

    ______________________________________                                                      Parts by Weight                                                   Ingredient     L       M         N    O                                        ______________________________________                                         LP-90          100     100       100  100                                      UVITHANE 893   75                                                              Polyester              75                                                      UVIMER 530                       75                                            NUPOL 46-8012                         75                                       CHEMLINK 600   25      25        25   25                                       Hydroxypropyl  20      20        20   20                                       methacrylate                                                                   Styrene        10      --        10   --                                       2% benzoquinone                                                                                5       5         5    5                                       in styrene                                                                     Zinc stearate  0.675   0.675     0.675                                                                               0.675                                    Calcium stearate                                                                              0.675   0.675     0.675                                                                               0.675                                    Cobalt octoate 0.225   0.225     0.225                                                                               0.225                                    (12% as Co in                                                                  mineral oil)                                                                   VULCAN carbon black                                                                           11      11        11   11                                       BEAVER WHITE   70      70        70   70                                       200, Talc                                                                      Brookfield viscosity                                                                          17,600  14,400    --   --                                       (cps) at 86° F., #7                                                     spindle at 100 rpm                                                             ______________________________________                                    

To each composition 1 part by weight of the initiator TBPB was added per 100 parts by weight of the total in-mold coating composition.

    ______________________________________                                         Gel Time at 230° F.                                                                  14.9/308 6.1/322   7.5/334                                                                              25.3/248                                 ______________________________________                                    

In-mold coating properties on molded thermoset glass fiberpolyester-styrene substrates:

    ______________________________________                                         Hot Strength                                                                               Good    Fair    Good    Fair                                       Adhesion (scapel, a                                                                        Pass    Pass    Fail    --                                         severe test) to                                                                substrate                                                                      Release from mold                                                                          Good    Good    Good    Did not mold                                                                   well - poor                                                                    cure caused                                                                    sticking                                                                       and poor                                                                       release                                    Phase separation                                                                           None    Yes     Excessive                                                                              --                                         Conductivity                                                                               165     165     --      --                                         (Ransberg meter                                                                reading)                                                                       ______________________________________                                    

Of Examples 4 and 5 Runs H, I and L were the best. Also, Run H possessed the best combination of hot strength, adhesion, mold release and conductivity. Run H, further, possessed superior hot strength as compared to Runs A, B, C, D, E, F and G of Examples 1 and 2.

EXAMPLE 6

The method of this example was similar to the preceding examples, and the following in-mold coating compositions were prepared:

    __________________________________________________________________________                 Parts By Weight                                                    Ingredient  P    Q   R   S    T    U    V                                      __________________________________________________________________________     LP 90       100.0                                                                               100.0                                                                              100.0                                                                              50.0 80.0 50.0 75.0                                   CHEMLINK 600                                                                               62.5 25.0                                                                               33.0                                                                               --   --   15.0 15.0                                   Hydroxy propyl                                                                             60.0  7.5                                                                               30.0                                                                               30.0 30.0 30.0 30.0                                   methacrylate                                                                   Styrene     --    2.5                                                                               --  40.0 32.0 40.0 35.0                                   2% benzoquinone in                                                                          5.0  5.0                                                                                5.0                                                                                5.0  5.0  5.0  5.0                                   styrene                                                                        Above mixed well and then there were added:                                    Zinc stearate                                                                              0.9  0.9 0.9 0.9  0.9  0.9  0.9                                    Cobalt octoate (12% as                                                                     0.12 0.12                                                                               0.12                                                                               0.12 0.12 0.12 0.12                                   Co in mineral oil)                                                             Above mixed well and then there was added:                                     EPOCRYL 370 62.5 75.0                                                                               67.0                                                                               75.0 75.0 75.0 85.0                                   Above mixed well and then there were added:                                    VULCAN carbon black                                                                        11.0 11.0                                                                               11.0                                                                               11.0 11.0 11.0 11.0                                   MISTRON RCS 80.0 80.0                                                                               80.0                                                                               80.0 80.0 80.0 80.0                                   Above mixed well.                                                              Properties of the resulting compositions:                                      Brookfield viscosity                                                                       --   --  --  24,000                                                                              22,600                                                                              21,600                                                                              20,400                                 (cps) at 86° F., #7                                                     spindle @ 100 rpm                                                              Gel time, 230° F. (1.5                                                              10.9/319                                                                            8.5/326                                                                            7.8/317                                                                            10.7/342                                                                            12.5/327                                                                            9.7/343                                                                             10.5/340                               pbw TBPB/100 pbw                                                               composition)                                                                   Properties on in-mold coating of FRP substrates with the                       compositions:                                                                  Adhesion, scalpel:                                                             FRP I substrate                                                                            Marg./                                                                              Marg./                                                                             Marg./                                                                             Marg.(2)                                                                            Marg.(2)                                                                            Marg.(2)                                                                            Marg.(2)                                           Fail Fail(1)                                                                            Fail                                                      FRP II substrate                                                                           --   --  --  Marg./                                                                              Marg.                                                                               Marg./                                                                              Pass                                                            Fail      Fail                                        Hot strength*                                                                              Poor Good                                                                               Fair                                                                               Excellent                                                                           Excellent                                                                           Excellent                                                                           Excellent                              (60 seconds cure)                                                              Hardness, pencil*                                                                          F    F   F   H    H    H    H                                      __________________________________________________________________________      *Essentially same for coatings on both substrates                              (1) Poorest adhesion                                                           (2) Best adhesion                                                        

Of Example 6, Run V possessed the best combination of hot strength and adhesion.

EXAMPLE 7

The method of this example was similar to the preceding examples, and the following in-mold coating compositions were prepared:

    __________________________________________________________________________                    Parts By Weight                                                 Ingredient     AA  BB  CC   DD  EE   FF                                        __________________________________________________________________________     LP 90          75.0                                                                               75.0                                                                               75.0 75.0                                                                               75.0 75.0                                      Hydroxy propyl methacrylate                                                                   30.0                                                                               30.0                                                                               30.0 30.0                                                                               30.0 30.0                                      Styrene        35.0                                                                               35.0                                                                               35.0 35.0                                                                               35.0 35.0                                      2% benzoquinone in styrene                                                                     5.0                                                                                5.0                                                                                5.0  5.0                                                                                5.0  5.0                                      Above mixed well and then there was added:                                     UVITHANE 782   15.0                                                                               30.0                                                                               --   --  --   --                                        UVITHANE 783   --  --  15.0 30.0                                                                               --   --                                        UVITHANE 893   --  --  --   --  15.0 30.0                                      Above mixed well and then there were added:                                    Zinc stearate   0.9                                                                                0.9                                                                                0.9  0.9                                                                                0.9  0.9                                      Calcium stearate                                                                                .45                                                                                .45                                                                                .45                                                                                 .45                                                                                .45                                                                                 .45                                     Cobalt octoate (12% as                                                                          .12                                                                                .12                                                                                .12                                                                                 .12                                                                                .12                                                                                 .12                                     Co in mineral oil)                                                             Above mixed well and then there were added:                                    EPOCRYL 370    85.0                                                                               70.0                                                                               85.0 70.0                                                                               85.0 70.0                                      Above mixed well and then there were added:                                    VULCAN carbon black                                                                           11.0                                                                               11.0                                                                               11.0 11.0                                                                               11.0 11.0                                      MISTRON RCS    80.0                                                                               80.0                                                                               80.0 80.0                                                                               80.0 80.0                                      Above mixed well. -                                                            Properties of the resulting compositions:                                      Brookfield vis (cps) 86° F.,                                                           --  20,000                                                                             --   15,200                                                                             --   --                                        #7 spindle @ 100 rpm                                                           Gel Time, 230° F. (1.5 pbw                                                             10.8/                                                                              10.9/                                                                              11.7/                                                                               10.7/                                                                              11.9/                                                                               13.6/                                     TBPB/100 pbw composition)                                                                     324 310 342  326 320  310                                       Properties on in-mold coating of FRP substrates with the                       compositions:                                                                  Hot Strength (60 secs. cure)                                                                  Good                                                                               Fair                                                                               Excellent                                                                           Good                                                                               Excellent                                                                           Good                                      Adhesion, scalpel:                                                             FRP I          Marg./                                                                             Marg.                                                                              Fail Marg.                                                                              Marg./                                                                              Marg.                                                    Fail             Fail                                           FRP III        --  Pass                                                                               --   Pass                                                                               --   --                                        FRP II         --  Marg.                                                                              --   Marg.                                                                              --   --                                        Hardness, Pencil                                                                              F   F   H    H   H    H                                         __________________________________________________________________________

Of Example 7 Run DD possessed the best combination of hot strength and adhesion.

EXAMPLE 8

The method of this example was similar to the preceding examples, and the following in-mold coating compositions were prepared:

    __________________________________________________________________________                    Parts By Weight                                                 Ingredient     GG   HH  II  JJ    KK                                           __________________________________________________________________________     EPOCRYL 370    100.0                                                                               70.0                                                                               70.0                                                                               70.0  70.0                                         LP 90          --   75.0                                                                               --  --    --                                           UVITHANE 783   --   --  30.0                                                                               --    15.0                                         CHEMLINK 600   --   --  --  30.0  15.0                                         Hydroxy propyl methacrylate                                                                   50.0 50.0                                                                               50.0                                                                               50.0  50.0                                         Styrene        50.0  5.0                                                                               50.0                                                                               50.0  50.0                                         2% benzoquinone in styrene                                                                     5.0  5.0                                                                                5.0                                                                                5.0   5.0                                         Above mixed well and then there were added:                                    Zinc stearate  0.9  0.9 0.9 0.9   0.9                                          Calcium stearate                                                                              0.45 0.45                                                                               0.45                                                                               0.45  0.45                                         Cobalt octoate (12% as                                                                        0.12 0.12                                                                               0.12                                                                               0.12  0.12                                         Co in mineral oil)                                                             Above mixed well and then there were added:                                    VULCAN carbon black                                                                           11.0 11.0                                                                               11.0                                                                               11.0  11.0                                         MISTRON RCS    80.0 80.0                                                                               80.0                                                                               80.0  80.0                                         Above mixed well.                                                              Properties of the resulting compositions:                                      Brookfield viscosity (cps) at                                                                 21,200                                                                              13,600                                                                             18,000                                                                             16,000                                                                               13,600                                       86° F., #7 spindle @ 100 rpm                                            Gel time, 230° F. (1.5 pbw TBPB                                                        12.8/                                                                               13.9/                                                                              12.9/                                                                              13.9/ 12/                                          /100 pbw of composition)                                                                      348  328 340 338   349                                          Properties on in-mold coating of FRP's with the compositions:                  Adhesion, scalpel:                                                             FRP I          Fail Marg.                                                                              Fail                                                                               Marg./Fail                                                                           Fail                                         FRP III        Fail Pass                                                                               Pass                                                                               Pass  Pass                                         FRP II         Fail Marg.                                                                              Marg.                                                                              Fail/Spotty                                                                          Marg./Fail                                   Hot Strength   Excellent                                                                           Fair/                                                                              Good                                                                               Fair  Good                                         (60 secs. cure)     Good                                                       Hardness, pencil                                                                              2H   2H  2H  F     2H                                           __________________________________________________________________________

EXAMPLE 9

The method of this example was similar to the preceding examples, and the following in-mold coating compositions were prepared:

    __________________________________________________________________________                    Parts By Weight                                                 Ingredient     LL  MM  NN  OO    PP                                            __________________________________________________________________________     LP 90          100.0                                                                              100.0                                                                              100.0                                                                              100.0 75.0                                          Hydroxy propyl methacrylate                                                                   30.0                                                                               30.0                                                                               30.0                                                                               35.0  35.0                                          Styrene        25.0                                                                               25.0                                                                               25.0                                                                               30.0  40.0                                          CHEMLINK 600   --  15.0                                                                               15.0                                                                               15.0  15.0                                          UVITHANE 782   30.0                                                                               --  15.0                                                                               15.0  15.0                                          2% benzoquinone in styrene                                                                     5.0                                                                                5.0                                                                                5.0                                                                                5.0   5.0                                          Above mixed well and then there were added:                                    Zinc stearate  0.9 0.9 0.9 0.9   0.9                                           Calcium stearate                                                                              0.45                                                                               0.45                                                                               0.45                                                                               0.45  0.45                                          Cobalt octoate (12% as Co                                                                     0.12                                                                               0.12                                                                               0.12                                                                               0.12  0.12                                          in mineral oil)                                                                Above mixed well and then there was added:                                     EPOCRYL 370    70.0                                                                               85.0                                                                               70.0                                                                               70.0  70.0                                          Above mixed well and then there were added:                                    VULCAN carbon black                                                                           11.0                                                                               11.0                                                                               11.0                                                                               11.0  11.0                                          MISTRON RCS    80.0                                                                               80.0                                                                               80.0                                                                               80.0  80.0                                          Above mixed well.                                                              Properties of the resulting compositions:                                      Brookfield viscosity (cps) at                                                                 21,600                                                                             19,200                                                                              19,600                                                                            14,800                                                                               13,600                                        86° F., #7 spindle @ 100 rpm                                            Gel time 230° F. (1.5 pbw                                                              8.3/                                                                               10.7/                                                                              9.6/                                                                               9.8/  9.7/                                          TBPB/100 pbw composition)                                                                     318 322 330 308   312                                           Properties on in-mold coating of FRP substrates with the                       compositions:                                                                  Adhesion, scalpel:                                                             FRP I          Marg.                                                                              Marg.                                                                              Marg./                                                                             Marg. Marg.                                                                Pass                                                    FRP III        Pass                                                                               Pass                                                                               Pass                                                                               Pass  --                                            FRP II         Pass                                                                               Marg./                                                                             Marg./                                                                             Marg./                                                                               Marg./                                                           Pass                                                                               Pass                                                                               Pass  Pass                                          Hot strength (60 secs. cure)                                                                  Fair                                                                               Good                                                                               Fair                                                                               Fair/Good                                                                            Fair/Good                                     Hardness, pencil                                                                              F   F   F   F     F-H                                           Conductivity   165+                                                                               165+                                                                               165+                                                                               --    --                                            __________________________________________________________________________

EXAMPLE 10

This example illustrates a preferred method for preparation of the in-mold coating composition prior to in-mold coating and curing. The ingredients were mixed in the order as shown below:

    ______________________________________                                         LP 90                     75.0 pbw                                             CHEMLINK 600              15.0 pbw                                             Hydroxypropyl Methacrylate                                                                               30.0 pbw                                             Styrene                   25.0 pbw                                             2% Benzoquinone in Styrene                                                                                5.0 pbw                                             1. Charge these materials to the reactor and blend.                            Styrene             5.0 pbw        6.47 pbw                                    Zinc Stearate      0.90 pbw                                                    Calcium Stearate   0.45 pbw                                                    Cobalt Octoate (12% as                                                                            0.120 pbw                                                   Co in mineral oil)                                                             ______________________________________                                    

2. Pre-blend the above materials and charge to the reactor. After adding the above charge, heat to 44° C. (110° F.) while mixing using a reflux condenser. Once the materials have reached 44° C., remove the heat and set-up to apply cooling water.

    ______________________________________                                         EPOCRYL 370 (Preheated to 47° C.)                                                              85.0 pbw                                                ______________________________________                                    

3. Add the EPOCRYL 370 to the reactor and mix until the material is uniform. During the addition of the EPOCRYL 370, cooling will be required to prevent the temperature from rising. After the EPOCRYL 370 has been added and mixed, cool to 38° C. (100° F.).

    ______________________________________                                         VULCAN carbon black                                                                               11.0 pbw                                                    ______________________________________                                    

4. Add the carbon black to the reactor and mix for 30 minutes. Hold the temperature at 38° C. (100° F.).

    ______________________________________                                         Talc (BEAVER WHITE 200)                                                                             80.0 pbw                                                  ______________________________________                                    

5. Add the talc to the reactor and mix for 1 hour while holding the temperature at 38° C. (100° F.). Remove sample.

Brookfield Viscosity (cps) 86° F., #7 Spindle @ 100 rpm, 10,000-14,000.

6. Check the gel time. If below 8 minutes, add 1 pbw of 2% benzoquinone in styrene and mix for 30 minutes. Recheck the gel time. Repeat the above procedure until the gel time is between 13 to 14 minutes.

    ______________________________________                                         Gel time,* 230° F.                                                                       14-16 minutes                                                 ______________________________________                                           *1.0 pbw of TBPB/100 pbw total composition. When making up material for       checking the gel time, weigh out 100.0 gms total composition and add 1.00      gm of TBPB and mix thoroughly before running gel test.                   

7. Add 1 additional part of 2% benzoquinone in styrene. Subtract the total number of the pbw of 2% benzoquinone in styrene additions made from the number 5 and add the difference as styrene. Mix for 30 minutes, degas for 15 minutes and filter through a 60 mesh screen. Store at 70° F. pbw--parts by weight.

Notes For The Examples

LP-90--BAKELITE LP-90-40% by weight of polyvinyl acetate in styrene, viscosity of 1,800 centipoises at 25° C. (Model LVT Brookfield viscometer #4 spindle at 60 rpm), specific gravity 20/20° C. (H₂ O=1) of 1.008 and solidification temperature of 5° C. Union Carbide Corp.

UVITHANE 783, a polymerizable urethane based material or oligomer, a diacrylate terminated polyesterurethane prepolymer. A viscous liquid (Kg/l 1.3 at 25° C.) having a viscosity at 49° C. of 600-2000 poise and at 82° C. of 50-110 poise, having an unsaturation (equiv./100 grams) of 0.17-0.205 and having an isocyanate content (%) of 0.3 max. Thiokol/Chemical Division, Thiokol Corporation.

CHEMLINK 600 or CL 600-Polyoxyethylene glycol 600 dimethacrylate. Molecular weight of about 770. C₃₆ H₆₆ O₁₇. The Ware Chemical Corp.

VULCAN--XC-72R. N472. Conductive furnace carbon black. Cabot Corp.

Talc--hydrous magnesium silicate.

TBPB--tertiary butyl perbenzoate.

EPOCRYL 370--Non-volatile diacrylate ester of a liquid Bisphenol A epoxy resin having a viscosity, poise, 25° C. (100% resin) of 9,000; and acidity eq./100 G of 0.007; an epoxide eq./100 G of 0.02; a Gardner color of 4; a weight/volume, lb/U.S. Gal, of 9.99; a flash point, °C.>204 and a viscosity, Gardner, 25° C. (80% w resin in xylene) of V-Y. Shell Chemical Co.

CHEMPOL 4825--(19-4825) Solvent free epoxy acrylate resin which contains active acrylic unsaturation on the polymer molecule. It has an acid number of 3-10; a color of 1-4; a viscosity, centipoise, of 4000-6000 at 140° F. and 1400-1800 at 160° F. and a weight per gallon of 9.8-10.0 lbs. It may contain up to 2% by weight of free acrylic acid. Freeman Chemical Corp.

UMIVER 580--A polyethylenically unsaturated liquid oligomer having a high reactivity in free radical polymerization. An amber colored liquid at room temperature having a mild characteristic odor. It has a viscosity (Gardner-Holdt) Z₆ -Z₇ (200-500 poises), a color (Gardner-Holdt) of 3 max., a weight of 9.6±0.1 lbs./U.S. gallon and a flash point (closed cup) of 210° F. (approx.). Polychrome Corporation.

ATLAC 382 E--It is a Bisphenol A--polyester resin. ICI Americas Inc.

UVITHANE 893--A polymerizable urethane oligomer, a viscous liquid. It has a color, APHA, of 110 max.; a mild odor; a weight of 10 lbs/gal at 77° F.; viscosity poises of 900-2200 at 120° F., 80-180 at 160° F. and 30-80 at 180° F.; an unsaturation equiv/100 g. of 0.150-0.175 and an isocyanate content of 0.2% max. Thiokol Corporation.

Polyester--A polyester made by the copolymerization of propylene oxide, ethylene oxide, maleic anhydride, fumaric acid and phthalic anhydride using a double metal cyanide catalyst. It has been isomerized, is OH terminated and has a molecular weight of about 1200.

UVIMER 530--A polyethylenically unsaturated liquid oligomer with extremely high reactivity in free radical polymerization. It has a viscosity (Gardner-Holdt) Z₇ -Z₈ (375-600 poises); a color (Gardner-Holdt) of 5 max.; a weight of 9.8±0.05 lbs. per U.S. gallon and a flash point (closed cup) of 210° F. (approx.). Polychrome Corporation.

NUPOL 46-8012--A mixture of 70% acrylate terminated polymer, 28% styrene and 2% hydroxyethyl methacrylate. Freeman Chemical Corp.

MISTRON RCS--Talc. Cyprus Industrial Chems.

UVITHANE 782--Acrylated urethane oligomer. Low melting solid, APHA color of 50 max., mild odor, lbs./gal at 77° F. (25° C.) (kg/l) of 10.2 (1.2), Viscosity in poises at 120° F. (49° C.) of 800-1600, @ 160° F. (71° C.) of 200-350 and @ 180° F. (82° C.) of 85-165, unsaturation equivalent/100 gms. of 0.04-0.05 and an isocyanate content % of 0.3 max. Thiokol/Chemical Division. 

What is claimed is:
 1. A composition useful as a thermosetting coating composition comprising(a) 100 parts by weight of at least one polymerizable epoxy based oligomer having at least two acrylate groups and a weight average molecular weight of from about 500 to 1,500, (b) from about 80 to 160 parts by weight of at least one copolymerizable ethylenically unsaturated monomer selected from the group consisting of styrene, alpha methyl styrene, vinyl toluene, t-butyl styrene, chlorostyrene, methyl methacrylate, diallyl phthalate (with styrene or methyl methacrylate), triallyl cyanurate, triallyl isocyanurate, divinyl benzene and methyl acrylate, (c) from about 10 to 120 parts by weight of at least one copolymerizable monoethylenically unsaturated compound having a --CO-- group and a --NH₂, --NH-- and/or --OH group, (d) from about 20 to 90 parts by weight of polyvinyl acetate, (e) from about 0.2 to 5 parts by weight of at least one zinc salt of a fatty acid having at least 10 carbon atoms, (f) from about 0.01 to 1.0 part by weight of at least one accelerator for a peroxide initiator, (g) from about 5 to 30 parts by weight of conductive carbon black, (h) from about 50 to 155 parts by weight of a filler and (i) from about 5 to 120 parts by weight of a copolymerizable or cocurable diacrylate compound having a weight average molecular weight of from about 250 to 5,000 and being selected from the group consisting of(I) at least one polyoxyalkylene glycol oligomer having two acrylate groups and (II) at least one polyurethane based oligomer having two acrylate groups and mixtures of (I) and (II).
 2. A composition according to claim 1 containing additionally at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
 3. A composition according to claim 1 where (H) comprises talc.
 4. A composition according to claim 3 containing additionally at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
 5. A composition according to claim 1 containing additionally (j) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight.
 6. A composition according to claim 5 containing additionally at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
 7. A composition according to claim 1 containing additionally (J) at least one calcium salt of a fatty acid having at least 10 carbon atoms in an amount of from about 0.2 to 5 parts by weight and where (h) comprises talc.
 8. A composition according to claim 7 containing additionally at least one organic free radical peroxide initiator in an amount of up to about 5% by weight based on the weight of the polymerizable ethylenically unsaturated materials.
 9. A composition according to claim 1 where(a) is a diacrylate ester of a liquid Bisphenol A epoxy resin, (b) is styrene, (c) is hydroxypropyl methacrylate, (e) is zinc stearate, (f) is cobalt octoate, (h) is talc and (i) is polyoxyethylene glycol dimethacrylate having a molecular weight of about
 770. 